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Preparation and Characterization of Homo and Heterobinuclear Complexes of Co+2, Ni+2, Cu+2, Zn+2, Cd+2 and Hg+2 with Tetramethylthiurammonosulfide

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    • Afyaa M. Younes
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Abstract

Some new homo and heterobinuclear complexes of Co(II), Cu(II), Ni(II), Zn(II) Cd(II) and Hg(II) with tetramethylthiurammonosulfide have been prepared in 2:2 molar ratio.The prepared complexes were characterized by their metal contents (Co, Ni, Cu, Zn, Cd and Hg), IR, electronic spectra , conductivity and magnetic measurements.
Conductivities data showed that the complexes were non electrolytes assigning the formulaes [M2(L)2CL4] or [MM´(L)2CL4]. Explanation for the structural elucidation of these complexes on the bases of magnetic and electronic measurements indicated that the complexes had tetragonal geometry with tetrahedral environment.

Keywords

  • Some new homo and heterobinuclear complexes of Co
  • and Hg
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College Of  Basic  Education  Research Journal
Volume 11, Issue 1
March 2012
Page 641-647
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APA

M. Younes, A. (2011). Preparation and Characterization of Homo and Heterobinuclear Complexes of Co+2, Ni+2, Cu+2, Zn+2, Cd+2 and Hg+2 with Tetramethylthiurammonosulfide. College Of Basic Education Research Journal, 11(1), 641-647.

MLA

Afyaa M. Younes. "Preparation and Characterization of Homo and Heterobinuclear Complexes of Co+2, Ni+2, Cu+2, Zn+2, Cd+2 and Hg+2 with Tetramethylthiurammonosulfide". College Of Basic Education Research Journal, 11, 1, 2011, 641-647.

HARVARD

M. Younes, A. (2011). 'Preparation and Characterization of Homo and Heterobinuclear Complexes of Co+2, Ni+2, Cu+2, Zn+2, Cd+2 and Hg+2 with Tetramethylthiurammonosulfide', College Of Basic Education Research Journal, 11(1), pp. 641-647.

VANCOUVER

M. Younes, A. Preparation and Characterization of Homo and Heterobinuclear Complexes of Co+2, Ni+2, Cu+2, Zn+2, Cd+2 and Hg+2 with Tetramethylthiurammonosulfide. College Of Basic Education Research Journal, 2011; 11(1): 641-647.

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