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New Metal(II) Complexes of 2-Hydroxy-N-(2-Hydroxynaph Thalene-1-yl) Methylene Benzohydrazide: Synthesis and Spectroscopic Studies

    Authors

    • Thafr E. Tawfik
    • Maher A.M. Altayy

    Department of Chemistry , College of Education for Girls ,‎University of Mosul, Mosul, Iraq

,

Document Type : Research Paper

10.33899/berj.2023.178134
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Abstract

    The study includes the preparation of complexes Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) with Schiff base ligand (HNMBH2) which is derived from the condensation reaction of 2-hydroxybenzohydrazide with 2-Hydroxy-1-naphthalene carboxaldehyde. The properties of which were characterized by infrared, magnetic measurements, molar conductivity measurements, electronic spectra, nuclear magnetic resonance spectra of 1H and13 C, and gas chromatography-mass spectrometry. It is found  that the ligand acts as neutral tridentate to give high-stability mononuclear complexes that have a tetrahedral or square planar structure.

Keywords

  • : hydrazides
  • benzohydrazide complexes
  • Schiff base
  • transition and non-transition elements
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College Of  Basic  Education  Research Journal
Volume 19, Issue 1
March 2023
Page 708-740
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APA

Tawfik, T., & Altayy, M. (2023). New Metal(II) Complexes of 2-Hydroxy-N-(2-Hydroxynaph Thalene-1-yl) Methylene Benzohydrazide: Synthesis and Spectroscopic Studies. College Of Basic Education Research Journal, 19(1), 708-740. doi: 10.33899/berj.2023.178134

MLA

Thafr E. Tawfik; Maher A.M. Altayy. "New Metal(II) Complexes of 2-Hydroxy-N-(2-Hydroxynaph Thalene-1-yl) Methylene Benzohydrazide: Synthesis and Spectroscopic Studies". College Of Basic Education Research Journal, 19, 1, 2023, 708-740. doi: 10.33899/berj.2023.178134

HARVARD

Tawfik, T., Altayy, M. (2023). 'New Metal(II) Complexes of 2-Hydroxy-N-(2-Hydroxynaph Thalene-1-yl) Methylene Benzohydrazide: Synthesis and Spectroscopic Studies', College Of Basic Education Research Journal, 19(1), pp. 708-740. doi: 10.33899/berj.2023.178134

VANCOUVER

Tawfik, T., Altayy, M. New Metal(II) Complexes of 2-Hydroxy-N-(2-Hydroxynaph Thalene-1-yl) Methylene Benzohydrazide: Synthesis and Spectroscopic Studies. College Of Basic Education Research Journal, 2023; 19(1): 708-740. doi: 10.33899/berj.2023.178134

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